Mon 26 Dec, 2011 4:29 pm
Tue 27 Dec, 2011 7:49 am
Tue 27 Dec, 2011 12:14 pm
Tue 27 Dec, 2011 12:43 pm
Tue 27 Dec, 2011 1:06 pm
etrangere wrote:Personally I find how Americanisms pervade other countries languages and cultures both sad and annoying so I stick to "metho", plus when I think of alcohol something to drink comes to mind not something to light a match to!
Tue 27 Dec, 2011 1:53 pm
Tue 27 Dec, 2011 3:49 pm
Tue 27 Dec, 2011 3:58 pm
Tue 27 Dec, 2011 5:15 pm
Oops, sorry, my bad. I just failed Cultural Sensitivity 101, didn't I? Yes, in Australian terms, they might well be called metho stoves.Gusto wrote:Why people always refer to these are other similar stoves as "alcohol sotves". Surely in Australian terms they are Metho stoves?
Consider yourself lucky. Metholated spirts make an excellent stove fuel. In many parts of the world, the US and Canada for example, metho just isn't available. One can buy something vaguely similar, but true metho is really good stuff, and you have to pay more for it in the US.Gusto wrote: Or do people use something other then Metholayted Spirits? if so, why?
Tue 27 Dec, 2011 5:18 pm
If you absolutely can't find them in Oz, send me a PM (or whatever they call them in Australia).Aushiker wrote:BTW does anyone know if the Zip Lock containers HJ refers to are available in our supermarkets? I know I should get down and have a look but I am allergic to shopping centres at this time of the year
Tue 27 Dec, 2011 5:20 pm
hikin_jim wrote:If you absolutely can't find them in Oz, send me a PM (or whatever they call them in Australia).Aushiker wrote:BTW does anyone know if the Zip Lock containers HJ refers to are available in our supermarkets? I know I should get down and have a look but I am allergic to shopping centres at this time of the yearI'm sure there's a way to hook you up. They're as cheap as chips here.
Tue 27 Dec, 2011 6:17 pm
Tue 27 Dec, 2011 6:55 pm
PurificationMain article: Ethanol purification
Ethylene hydration or brewing produces an ethanol–water mixture. For most industrial and fuel uses, the ethanol must be purified. Fractional distillation can concentrate ethanol to 95.6% by volume (89.5 mole%). This mixture is an azeotrope with a boiling point of 78.1 °C, and cannot be further purified by distillation.
Common methods for obtaining absolute ethanol include desiccation using adsorbents such as starch, corn grits, or zeolites, which adsorb water preferentially, as well as azeotropic distillation and extractive distillation. Most ethanol fuel refineries use an adsorbent or zeolite to desiccate the ethanol stream.
In another method to obtain absolute alcohol, a small quantity of benzene is added to rectified spirit and the mixture is then distilled. Absolute alcohol is obtained in the third fraction, which distills over at 78.3 °C (351.4 K).[14] Because a small amount of the benzene used remains in the solution, absolute alcohol produced by this method is not suitable for consumption, as benzene is carcinogenic.[40]
There is also an absolute alcohol production process by desiccation using glycerol. Alcohol produced by this method is known as spectroscopic alcohol—so called because the absence of benzene makes it suitable as a solvent in spectroscopy.
Rectified spiritsRectified spirit, an azeotropic composition containing 4% water, is used instead of anhydrous ethanol for various purposes. Wine spirits are about 188 proof. The impurities are different from those in 190 proof laboratory ethanol.[46]
Absolute ethanol Absolute or anhydrous alcohol refers to ethanol with a low water content. There are various grades with maximum water contents ranging from 1% to ppm levels. Absolute alcohol is not intended for human consumption. If azeotropic distillation is used to remove water, it will contain trace amounts of the material separation agent (e.g. benzene).[43] Absolute ethanol is used as a solvent for laboratory and industrial applications, where water will react with other chemicals, and as fuel alcohol. Spectroscopic ethanol is an absolute ethanol with a low absorbance in ultraviolet and visible light, fit for use as a solvent in ultraviolet-visible spectroscopy.[44]
Wed 28 Dec, 2011 2:33 am
Wed 28 Dec, 2011 5:55 am
Well, yes, but mentholated spirits have such a nice, minty scent don't you think?Mark F wrote:And for some others it is methYlated not methOlated and certainly not "mentholated".
Horrifying. Yes, theoretically, the liver will be preferentially engaged with the ethanol, but would I take the risk of imbibing methanol? Risks did you say? Oh, yes, a couple of "minor" side effects like permanent blindness or even death.Mark F wrote: I have seen, many years ago, metho in the drinks fridge of a supermarket in Wilcannia. No doubt for the "benefit" of the local indigenous population. A flagon of cheap sherry + a bottle of metho was unfortunately a common drink.
Wed 28 Dec, 2011 7:05 am
hikin_jim wrote:Thank you, Tony, I'd love to play with either variety, but short of making connections with someone from a university or lab, I'll probably have to content myself with the 190 proof type one buys at a liquor store as the best I can reasonably get. Honestly though, I'll probably mostly use either methanol or the stuff that passes for metho here (roughly 50/50 methanol/ethanol with a smattering of other nasties), both of which can be had for about $4.50/liter. 190 proof is expensive, illegal in my state, and, well, it seem such a shame to burn something so dear.
I dream of nice 95/5 Aussie metho at night.Well, not really, but it surely would be nice to have 95/5 readily available.
HJ
Wed 28 Dec, 2011 8:17 am
Oh, that's right. I had forgotten about that article. I think you and I have talked about that before.Tony wrote:A mix of 50/50 ethanol methanol is still quite a good mixture, if you go to mine and Roger Caffins The Performance of Alcohol Fuels for Backpacking Stoves Part One: Three Straight Alcohols and Alcohol Blends you will see that boiling 500 mls of water with Ethanol we used just under 11g of fuel with Methanol we used just over 13g of fuel and with a 50/50 blend we used just under 12g of fuel or 1g more per 500ml than straight Ethanol, so if you boil 10 liters of water on a trip that is 20g extra fuel if you use a 50/50 blend, not much really.
Wed 28 Dec, 2011 8:04 pm
In the conditions I was testing under (see the bottom of the blog post) and with the equipment I was testing with, I found a 6ml (~5g) difference between a high ethanol content fuel and methanol. My testing is no where near as good as yours, and I'm running out in the open where there are a thousand uncontrolled variables, but none-the-less, the results were fairly consistent across multiple tests. And I do run a lot of tests. Yesterday, I started testing around 1500 PST and finished testing around 2030 PST.
I started testing around 1500 PST and finished testing around 2030 PST. My wife was about to call Search and Rescue because I hadn't brought our daughter home by almost 2200. I still have to walk back out to the road after my testing, which in the dark carrying about 25kg* (including my daughter) is no small trick
*In addition to my daughter, I carried ten stoves, four windscreens, three pots, three different classes of fuel (propane, Shellite, and metho), a variety of pot stands, and a remote canister rig as well as food, water, and equipment for two people. What was I thinking?
Thu 29 Dec, 2011 1:59 am
I have some thoughts, call them semi-educated speculation, as to why our results may be different.Tony wrote:As you know stove testing is not an exact science, I am not sure why I got different results than you. My tests where done under the same controlled conditions and all weight measurements where done to an accuracy of 0.1g and the temperature to 0.1C, the results are the average of three tests. I have also spent many hours and days testing.
© Bushwalk Australia and contributors 2007-2013.